As I wrote in the duplicate bug report: It works on a fresh user account. On an existing account, the configured keyboard shortcuts may not be updated though. That's more or less an upstream issue (and not a new one, KDE4 had/has the same problem). I'm not sure if we can do anything about it. I'll have a look, maybe a kconf_update script might be able to change it. But the actual problem lies deeper than spectacle or the PrtScr key assignment and is probably by design.